Solidification/Stabilization of MSWI Fly Ash Using a Novel Metallurgical Slag-Based Cementitious Material
نویسندگان
چکیده
Four industrial wastes, i.e., blast furnace slag, steel desulfurization ash, and phosphoric acid sludge, were used to prepare a low-carbon binder, metallurgical slag-based cementitious material (MSCM). The feasibility of solidification/stabilization municipal solid waste incineration (MSWI) fly ashes by MSCM evaluated, the immobilization mechanisms heavy metals proposed. paste achieved 28-day strength 35.2 MPa, showing its high-hydration reactivity. While ash content was as high 80 wt.%, MSCM-fly blocks reached 2.2 leaching concentrations Pb, Zn, Cr, Hg much lower than limit values Chinese landfill standard (GB 16889-2008). rates each metal 98.75–99.99%, while four kinds MSWI solidified at 60 wt.%. binder-fly had an increase 104.92–127.96% using replace ordinary Portland cement (OPC). Correspondingly, leachability compared OPC. treatment investigated XRD, SEM, TG-DSC. Numerous hydrates, such calcium silicate hydrate (C-S-H), ettringite (AFt), Friedel’s salt, observed in hardened pastes. Heavy from both could be effectively immobilized via adsorption, cation exchange, precipitation, physical encapsulation.
منابع مشابه
An Experimental Study on Utilization of Slag and Fly Ash as an Alternative Cementitious Binder
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Municipal solid waste incineration fly ash is generated in a significant amount; it is classified as hazardous waste in Taiwan. In order to reduce the volume of treated fly ash, a sintering technology can be considered. However, a traditional sintering consumes too much energy because of the limit of heat transfer. Hence, a microwave process which can provide quick, uniform, and selective heati...
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ژورنال
عنوان ژورنال: Minerals
سال: 2022
ISSN: ['2075-163X']
DOI: https://doi.org/10.3390/min12050599